Showing posts with label Biochemicals. Show all posts
Showing posts with label Biochemicals. Show all posts

Friday, October 21, 2011

What is next of biofeuls and biochemicals?

Recently I have been in AIChE annual meeting at Minneapolis, MN. There I sensed a different atmosphere compared to what I felt last year: Less attendance and pessimistic in biofuels.

Indeed, in the past twenty years, DOE and other government agents spent tons of money to support technology development in biofuel production from biomass. People are expecting a sun-rising industry like IT in the past to boost the economy. Therefore, green technology once became a hot green waves hitting every aspects of people’s life, especially for biofuels. Unfortunately, the current dominant technologies claimed in patents and highlighted for biofuel production from biomass have actually been existing there for hundreds of years; none of them seems to solve the cheap sugar problem. Therefore, some anti-biofuel people even anticipate that there would be no biofuels in the next 20 years.

It is true that at least cellulosic bioethanol will be dead if these technologies continue to control the government funding for 10 years. It really needs game-changing technology. Among all of the highlighted technologies, Agrivida technology recently stands out from nowhere and looks like a real solution for cheap sugar production from if it works as it claims. Therefore, hope is still shining somewhere as long as creativity is alive.
In addition, more interests and attention are shifting toward hydrocarbon fuel production from lignocellulosic biomass.  And more value-added biochemicals are being produced from biomass although not heavily funded by government funding.  Although a lot of uncertainty still exists for biofuels and biochemicals, one thing that never changes is that they are from renewable resources. Biodegradable materials and chemicals may become leading green products in the near future.

Thursday, April 23, 2009

Low Risk Biorefinery: more product streams

Bioethanol production often faces survival challenging due to its lower margin profit at low oil price and downturn economic recession, which always puts a sole-ethanol production business in a high risky situation. Although there is an incentive from government support with policy, funding, and tax credit, whether it is sustainable profitable will determine the future of this industry. The relatively safe way is to have multiple bio-product streams that are composed of high value-added biochemicals such as lactic acid, succinic acid, glucaric acid to reduce the risks.
US-DOE top 12 building blocks give us the direction.

Friday, November 7, 2008

Xylose to Acetic Acid?

In hardwood, there are about 7 acetyl groups per 10 xylose units, which can be easily cleaved under alkali conditions.

Instead of converting xylose to ethanol by direct fermentation, it may make acetic acid via fermentation of xylose to acetic acid.

2C5H10O5→5C2H4O2

Therefore, 10 moles of xylose can generate 32 moles of acetic acid because 10 moles of xylose has 7 moles of acetic acid and 10 moles of xylose can be fermented to 25 moles of acetic acid.

Y.Y. LEE reported a total 76 wt% conversion and a maximum acetate concentration of 15.2g/L (2001); Parekh and Cheryan were able to achieve final broth concentrations of 102 g/l (as HAc) with 93% conversion of the glucose feedstock using dolime (Ca(OH)2Mg(OH)2) for pH control in a fed batch fermentation with cell recycle provided by cross-flow membrane filtration.